Page 169 - Nomenclature of Inorganic Chemistry (IUPAC Recommendations 2005)
P. 169
Subject Index
and diastereoisomers, 179–180 formulae, 59–61, 153–154
octahedral systems, 182–183 construction, 59
reference axis, 182 enclosing marks, 18–19, 153
priming convention, 195–198 and ionic charge, 153–154
priority numbers, 180–181, 193–195 ligand abbreviations, 154
see-saw systems, 185 oxidation number, 153–154
square planar systems, 180–181 sequence of symbols, 153
square pyramidal systems, 183–184 square b rackets, 113–117
T-shaped systems, 185 k convention, 155–160
trigonal prismatic systems, 190 and Z convention, 161
Connectivity use of superscripts, 156
in chain and ring compounds, 118 ligand priority, 193–198
in organometallic compounds, 2 01–203, priority numbers, 1 80–181, 193–195
216 names, 144, 150–153
Constitution of coordination compounds, numbering of ligands, 1 50–151
149–174 order of ligands and central atoms,
formulae, 153–154 150
names, 150–153 representing ligands, 1 51–152
polynuclear species, 1 61–174 naming procedure, 1 49–150, 168
specifying donor atoms, 154–161 flowchart, 149–150
Coordination compounds and entities, polyhedral symbols, 33–34, 144,
142–199 175–179
absolute c onfiguration, 185–198 polynuclear clusters, 172–174
C/A convention, 185, 187–191 central structural unit, 172–174
distinguishing enantiomers, 185–193 CEP descriptors, 172–174
general considerations, 185 polynuclear compounds, 161–174
octahedral species, 189–190 bridging l igands, 148, 163–165
R/S convention, 185–186 metal–metal bonding, 165–166
see-saw species, 1 88 specifying configuration, 179–185
skew-lines convention, 185, 191–193 bipyramidal species, 184–185
square pyramidal species, 1 88 configuration index, 179–180
tetrahedral species, 1 86 distinguishing d iastereoisomers,
trigonal bipyramidal s pecies, 1 87 179–185
trigonal pyramidal species, 1 86 general methods, 179–180
CIP rules, 44, 180, 194–195 octahedral species, 1 82–183
configuration, 149, 174–193 square p lanar species, 1 80–181
general considerations, 174–175 square p yramidal species, 1 83–184
polyhedral s ymbols, 1 75–178 T-shaped species, 1 85
configuration index, 33–34, 144, specifying donor atoms, 154–161
179–180 italicized element s ymbols, 1 55–156
priming convention, 195–198 trinuclear species, 1 67–172
constitution, 149–174 Coordination nomenclature, 7, 147–148
definitions, 144–148 Coordination number
dinuclear species, 1 66–167 in organometallics, 201–202
symmetrical, 166 polyhedral symbols, 176
unsymmetrical, 1 66–167 Coordination polyhedra, 145–146, 176–178
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