Page 166 - Nomenclature of Inorganic Chemistry (IUPAC Recommendations 2005)

Subject Index

Boron compounds coordination compounds, 148
order of components of addition polynuclear species, 1 63–165
compounds, 1 2, 81 hydrogen in boranes, 28, 35, 93–94
oxoacids, 127, 137 heteroboranes, 9 9–100
table of names, 285 substitution, 104–105
Boron hydrides in organometallic compounds, 2 03,
bridging h ydrogen atom distribution, 28, 211–212
35, 93–94 bridge index, 43–44, 208–209
heteroboranes, 99–100 vs. c helation, 203, 208–209
catena prefix for chains, 91–92 position in names, 25
common structure types, 90 in symmetrical d inuclear entities,
arachno, 9 0–93, 99, 259 115–116
closo, 9 0–92, 99–100, 259 use of m symbol, 36, 163, 259
hypho, 9 0, 259 multiplicity, 32–33
klado, 9 0, 99–100 Bromic acid, 131, 287
nido, 9 0–94, 99–100, 259 Bromide, 287
relationships, 90–92 Bromido, 138, 287
cyclic compounds, 92 Bromine compounds and species, n ames,
cyclo prefix, 92 287, 298, 319–321
Hantzsch–Widman system, 9 2 Bromo
electron counting in clusters, 90 obsolete ligand name ( see bromido)
hydrogen substitution, 104–105 prefix in substitutive nomenclature, 101,
indicated hydrogen, 35, 93–94 138, 287
number of boron atoms, 89 Bromous acid, 131, 287
number of hydrogen atoms, 34, 90
in heteroboranes, 99 C
numbering polyhedral clusters, 92–93 C/A convention and absolute configuration,
closo vs. nido, 9 2 185, 187–191
order of symbols in carbaboranes, 60 bipyramidal complexes, 190–191
positions of supplanting heteroatoms, pentagonal species, 191
99–100 trigonal s pecies, 1 87
replacement nomenclature, 99 general considerations, 187
skeletal replacement, 98–100 octahedral complexes, 189–190
stoichiometric names, 89–90 polydentate ligands, 1 90
structural d escriptor names, 90–92 priming convention, 190
substituent g roups, 1 04–105 see-saw centres, 188
Boronic a cid, 127 square p yramidal complexes, 188
Braces, in formulae and names, 24 trigonal p rismatic complexes, 190
Bravais lattice, and allotrope names, 50 Caesium vs. cesium, 249
Bridging index, 43–44 Cahn, Ingold, Prelog (CIP) rules for
organometallic compounds, 208–209 coordination compounds, 44, 180,
polynuclear coordination compounds, 194–195
148, 163–165 octahedral species, 1 89
Bridging ligands trigonal p rismatic species, 1 90
citation vs. t erminal ligands, 4 3–44, Carbaboranes, 99–100
163–164 order of B a nd C i n f ormulae, 60

344