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IR-6.2                               S U B S T I T U T I V E  N O M  E N C L A T U R E





                                      fluorane d  chlorane d  bromane d  iodane d  astatane d  the  form  any  m  1  in  the  of  radicals  etc.  a However,  ‘indiane’


                                                     they  Ref.  heteromonocycles  name  ions,  bromide’,  acceptable.  name  mono-unsaturated
                                                     and  of  derived  of  IR-5).  The
                                                     nomenclature,  Section  In  six-membered  systematically  substitutive  fluoride’,  no  are  Chapter  2,3-dihydroindene.  as  well  as
                                      HF  HCl  HBr  HI  HAt  P-62  names  ‘hydrogen  longer  the




                                      xidane b,c  ulfane c,f  selane c,f  tellane c,f  polane c,f  recommended.  substitutive  IX.  Table  saturated  the  because  alanine.  acid  of formation  ‘hydrogen  ‘stibine’  and  nomenclature,  diene)  (a  bonds  indium).  of





                                                   not  by  and  IR-6.4  of  names  discarded  amino  the  named  ‘arsine’  (compositional  hydrocarbon  double  colour
                                          H 2 Se  H 2 Te  H 2 Po  is  respectively,  the  the  for  basis  be  names.  ‘phosphine’,  polane.  the  of  two  flame
                                      o
                                        s
                                                   carbane’  Section  ‘imine’.  are  they  be  must  from  the  also  parent  and  name  with  the
                                      H 2 O
                                        H 2 S
                                                   CH 4 ,  ‘  for  water,  and  in  found  and  since  ut  b  AlH 3 ,  derived  group  are  they  may  as  used  names  The  sulfide’  tellane  the  as  ompound  (from  ‘indigo’

                                      azane b  phosphane e  arsane e  stibane e  bismuthane c  ‘methane’  ammonia  of  be  may  use  ‘amine’  suffixes  used  be  cannot  for  used  acyl  the  because  here  hydrides  be  cannot  book.  ‘dihydrogen  selane,  to  established  c  mean  a  source



                                                   name  derivatives  such  group  been  of  name  included  unsubstituted  names  this  better,  apply  well  could  etymological
                                      NH 3  PH 3  AsH 3  SbH 3  BiH 3  the  of  polonane  has  throughout  or,  remarks  however,
                                                   of         ‘alane’  are  The   ‘triindiene’
                                                     naming u   well-established  ‘astatane’  used  which  e.g.
                                                   se   Examples  substituent  and  compositional  sulfide’  is,  the
                                                   universal  in  use  for  dioxidane).  the  of  tellurane  name  The  the  and  examples).  for  these  are ‘stibane’  ‘hydrogen  Corresponding  ‘indane’  derivatives,  from  derives


                                 hydrides  methane a  silane  germane  stannane  plumbane  the  of  Because  intended  triazane,  basis  the  on  selenane,  thiane,  IR-6.2.4.3).  is  which  ‘iodane’  IX  Table  However,  and  named  be  name.  arent  be  would  unsaturated  ‘indigane’



                                 mononuclear  CH 4  SiH 4  GeH 4  SnH 4  PbH 4  ‘carbane’.  only  are  (e.g.  named  are  oxane,  Section  ‘alanyl’  ‘bromane’,  and  IR-5).  Chapter  ‘arsane’  also  may  p  as  a  InH 3  for  name




                                 of                is  ‘oxidane’  entities  bismane,  (see  be  would  ‘chlorane’,  IR-6.4.7  ‘phosphane’,  used  be  name  naming  parent
                                 names             analogue  and  polynuclear  ammonia  system   AlH 2  (see  nomenclature,  unsubstituted,  cannot  systematic  when  The


                                 Parent  borane  alumane c  gallane  indigane g  thallane  ‘azane’  of  aluminane,  group  ‘fluorane’,  groups  names  name  confusion  triindiane.

                                 IR-6.1            systematic  names  naming  for  derivatives  names  Hantzsch–Widman  names  substituent  (compositional  systematic  when  compositional  analogous  to  lead  of

                                 Table  BH 3  AlH 3  GaH 3  InH 3  TlH 3  a  The  b  The  basis  organic  c  The  the  substituent  d  The  and  e  The  f  Sulfane,  g  The  would  derivative




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