Page 123 - Nomenclature of Inorganic Chemistry (IUPAC Recommendations 2005)

A D D I T I V E N O M E N C L A T U R E IR-7.3

12. [Te(C 5 H 9 )Me(NCO) 2 ]
Me

Te
NCO
NCO

bis(cyanato-N)(cyclopentyl)(methyl)tellurium (additive),
4
or cyclopentyldiisocyanato(methyl)-l -tellane (substitutive)

13. [Al(POCl 3 ) 6 ] 3þ hexakis(trichloridooxidophosphorus)aluminium(3þ)
14. [Al(OH 2 ) 6 ] 3þ hexaaquaaluminium(3þ)
15. [H(py) 2 ] þ bis(pyridine)hydrogen(1þ)
16. [H(OH 2 ) 2 ] þ diaquahydrogen(1þ)
17. [BH 2 (py) 2 ] þ dihydridobis(pyridine)boron(1þ)
18. [PFO 3 ] 2 fluoridotrioxidophosphate(2 )
19. [Sb(OH) 6 ] hexahydroxidoantimonate(1 ) ( additive),
5
or hexahydroxy-l -stibanuide (substitutive)
20. [HF 2 ] difluoridohydrogenate(1 )
21. [BH 2 Cl 2 ] dichloridodihydridoborate(1 ) ( additive),
or dichloroboranuide (substitutive)
22. OCO * dioxidocarbonate( * 1 )
23. NO (2 *) oxidonitrate(2 * 1 )
* 2
24. PO 3 trioxidophosphate( * 2 )
25. [ICl 2 ] þ dichloridoiodine(1þ) ( additive),
or dichloroiodanium (substitutive)
26. [BH 4 ] tetrahydridoborate(1 ) ( additive),
or boranuide (substitutive)

27. CH 5 pentahydridocarbonate(1 ) ( additive),
or methanuide (substitutive)
28. [PH 6 ] hexahydridophosphate(1 ) ( additive),
5
or l -phosphanuide (substitutive)
29. [PF 6 ] hexafluoridophosphate(1 ) ( additive),
5
or hexafluoro-l -phosphanuide (substitutive)

IR-7.3 P O L Y N U C L E A R E N T I T I E S

IR-7.3.1 Symmetrical dinuclear entities

In symmetrical d inuclear entities, each of the central atoms is of the same e lement and they
are identically ligated. Below, a dditive names of several formats a re given t o a number of

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