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2.6 Structure of nanomaterials


                 2D nanomaterials - synthesis









                  • Epitaxy:


                          • thin orientated layers of similar crystal structures

                          • e.g. InAs: a=603,6 pm on GaAs: a=565,4 pm, both sphalerite structures



                  • CVD (Chemical Vapour Deposition)


                          • decomposition of molecules in the gas phase by electron beam or laser
                          • deposition on suitable substrates

                          • e.g. fabrication of LEDs with GaP and GaAs P ,
                                                                                                      1-x
                                                                                                            x
                            epitaxial layers are produced by thermal decomposition

                            of compounds like AsH , AsCl , PH , PCl , ...
                                                                                         3
                                                                                                  3
                                                                     3
                                                                                3


                  • MBE
                                                                                 Production of a Ga Al As
                                                                                                              1-x
                                                                                                                    x
                                                                               on GaAs by the MBE process
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