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2.3 Basic structure types
Bonding in ionic structures - repulsion
Repulsion arising from overlap of electron clouds
Because the electron density of atoms
decreases exponentially towards zero at
large distances from the nucleus the
r 0 Born repulsion shows the same
behaviour
r
approximation:
B
V Born
r n
B and n are constants for a given atom
type; n can be derived from
compressibility measurements (~8)