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2.3 Basic structure types


                 Bonding in ionic structures - repulsion







                                      Repulsion arising from overlap of electron clouds






                                                                            Because the electron density of atoms
                                                                          decreases exponentially towards zero at


                                                                             large distances from the nucleus the

                                        r 0                                      Born repulsion shows the same

                                                                                                      behaviour

                                                                  r

                                                                                                  approximation:




                                                                                                                       B

                                                                                                   V    Born      

                                                                                                                      r  n



                                                                           B and n are constants for a given atom

                                                                           type; n can be derived from
                                                                           compressibility measurements (~8)
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