Page 168 - Nomenclature of Inorganic Chemistry (IUPAC Recommendations 2005)
P. 168
Subject Index
Chelate rings cis-bis(bidentate) complexes, absolute
conformation and skew-lines configuration and skew-lines
convention, 193 convention, 191–193
symbols for absolute configuration, closo-boranes, 90–92, 99–100, 259
35–36, 259 Clusters
Chelating ligands boranes, 90
vs. b ridging, 203, 208–209 numbering, 92–93
in organometallics, 202–203, 2 09–210 structural descriptors, 170, 172–174
k convention, 2 10–211 central structural units, 172–174
Chelation Cobaltocene, 225
in coordination compounds, 1 46 Colons
and k convention, 156–160 and central atom locants, 164
vs. m onodentate bonding, 147 in names, 28
in organometallic compounds, 202 Commas in formulae and names, 29
Chemical c omposition of solids, Commensurate s tructures, 242–243
237–238 Composition of non-stoichiometric
Chemical t winning, 244–245 compounds, 21
Chiral centres, 36 Compositional n omenclature, 5–6, 68–82
Chloric acid, 295 addition compounds, 80–81
Chloride, 294 generalized stoichiometric names,
Chlorido, 138, 294 75–80
Chlorine compounds and species, n ames, vs. hydrogen nomenclature for
294–295, 299, 319, 312–322 inorganic acids, 136
Chloro of ions, 70–75
obsolete l igand name (see chlorido) heteropolyatomic anions, 74–75
prefix in substitutive nomenclature, 138, heteropolyatomic cations, 71–72
294 homopolyatomic a nions, 8, 73–74
Chlorous acid, 131, 294 homopolyatomic c ations, 71
Choice monoatomic anions, 72–73
between geometries for coordination monoatomic cations, 7 0–71
compounds, 1 79 order of constituents, 41
of central atom in additive names, of radicals, 70–75
112 anions, 73–75
of nomenclature system, 7–9 cations, 7 0–72
of parent hydride names, 101 stoichiometric names, 68–70
principal chain, 103–104 binary compounds, 69–70
Chromium oxides, names, 295–296 elements, 69
Chromocene, 225 Configuration of coordination entities, 149,
CIP (Cahn, Ingold, Prelog) rules for 174–193
coordination compounds, 44, absolute configuration, 185–198
180, 194–195 coordination geometry, 175–179
octahedral species, 1 89 ligand priority, 193–198
trigonal prismatic species, 190 relative configuration, 179–185
cis prefix, 67, 179, 259 Configuration index, 33–34, 144, 179–180
and octahedral geometry, 182 bipyramidal systems, 184–185
and square p lanar geometry, 180 CIP rules, 180
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