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2.1 Basics of Structures
Unit cells and crystal system
• millions of structures but 7 crystal systems
• crystal system = particular restriction concerning the unit cell
• crystal system = unit cell with characteristic symmetry elements (later)
Crystal system Restrictions axes Restrictions angles
Triclinic - -
Monoclinic - °
Orthorhombic - °
Tetragonal a = b °
Trigonal a = b °°
Hexagonal a = b °°
Cubic a = b = c °